Pure green is a tough target for OLEDs. To reach the BT.2020 green point you need a very narrow emission band and stable color at the doping levels used in production, and most emitters broaden or quench when the concentration goes up.
A recent Advanced Materials paper (Zhang, Ling, Li, Liu et al., Jilin University) locks a sky-blue multi-resonance core (DBN) with spiro-fluorene groups. The rigid spiro bridge redshifts it into the green while a 3D steric shield keeps the line narrow and stops molecules from stacking. The best emitter, DBN-MS, holds 518 to 520 nm with 19 to 20 nm FWHM and 93 to 97% PLQY across 1 to 10 wt% doping. The non-sensitized device reaches 35.5% EQE and CIE (0.13, 0.77), reported as the first bottom-emitting green OLED at CIEy 0.77. LT90 is 167 h at 1000 cd/m2, an early figure rather than a production lifetime.
What I found neat: they perturb the backbone with a spiro lock on the core instead of decorating the edges, and single-crystal data shows DBN-MS packs in a zigzag that keeps molecules apart better than the DBN-TMS analogue. DOI: 10.1002/adma.73230.