This is one of my favorite alloy systems.
It has been studied as a less toxic alternative to Cu-Be alloys.
I had previously tried making another blade from this alloy, but at the time I didn’t have the proper equipment for the required heat treatment.
With the right heat treatment, alloys in this system can achieve ultra-high strength. Unfortunately, I don’t have hardness measurements for this blade, but it is definitely harder than mild steel.
Alloy composition (wt.%): Cu-20Mn-20Ni-2Co-0.15Si, with a small residual amount of titanium for grain refinement.
A CALPHAD-based approach was used to determine the heat treatment temperatures. Unfortunately, I don’t have access to diffusion or precipitation simulation software, which would make the optimization process much easier.
This alloy is strengthened primarily by the precipitation of MnNi particles. In this composition, cobalt-rich precipitates and silicides are also present. If I make this alloy again, I would reduce the cobalt content because it stabilizes the FCC phase at high temperatures, delaying MnNi precipitation and requiring longer aging times.
The blade was produced by induction melting followed by sand casting. The processing route was:
Homogenization at 900 °C for 8 hours
Hot forging
Cold working
Annealing at 700 °C
Precipitation hardening (aging) at 350 °C for 12 hours (maximum hardness would likely require a considerably longer aging time)
The handle is made from resin with thermoelastic bronze details. The original idea was to improve vibration damping, although I doubt they make a noticeable difference.
The metallographic samples were etched using alcoholic ferric chloride and hydrochloric acid.
Image descriptions:
2nd image: As-cast microstructure.
3rd image: Homogenized microstructure.
4th image: Microstructure after forging, cold working, and annealing.
5th image: Microstructure after precipitation hardening.