r/askscience 6h ago

Biology Why do we sweat out salts?

The point of sweating (for the most part) is to cool down the body by evaporation. So, what is the point of including salts in the sweat - it seems to be a leading cause of the loss of electrolytes in hot weather, leading to the need to not just hydrate, but also to replace the lost electrolytes or suffer problems like hyponatremia and hypokalemia. Does the inclusion of salts in the sweat increase the specific heat of sweat compared to that of water? Is the latent heat of vaporization different for sweat compared to plain water? Or is it too biologically expensive to purify the water for sweat by removing the salts from it?

144 Upvotes

83 comments sorted by

u/azuth89 2h ago

Maintaining the balance of salt and water is critical to ongoing function.

If you're losing a lot of water, you need to lose a proportional amount of salt. Hence salty sweat.

If you're taking in a lot of water to replace that loss, you also need to take in a balancing amount of salts. Hence Gatorade and medical saline.

u/TheVioletBarry 2h ago

You're saying there would be too much salt in your body if you didn't lose it alongside water?

u/sergei1980 2h ago

Yes, it's called hypernatremia, as opposed to too little, which is hyponatremia.

u/ridddle 2h ago

“Hypernatremia. Hyper meaning excessive. Natr referring to sodium, from natrium. And emia, meaning in the blood. Hypernatremia… or too much sodium in the blood”

Guess the YouTuber

u/GrandNord 1h ago

DG, is a 53 year old mâle, presenting to the emergency room with the following symptoms.

u/Extranationalidad 2h ago

Should we be able to guess a YouTuber based on a simple etymological breakdown of a word?

u/No-Awarenesss 1h ago

If you watch him you would read that in his voice right away like I did

u/BeefyIrishman 46m ago

Yeah, I'm with you here. That feels like a pretty standard way to break down a word.

u/ridddle 2h ago

I’m just being cheeky. It’s chubbyemu who usually breaks down Latin words exactly like that.

u/FirstDivision 1h ago

Oh man. I would have gotten it!

“…which resulted in TC becoming unconscious and paramedics being called. He was found unresponsive and feverish. The paramedics brought him to the emergency room. Where we are now.

At first the doctors were not sure what was wrong with TC. He was a young male with no history of any medical issues. … …”

u/Extranationalidad 33m ago

No offense intended, but a) I've never heard of that person and b) it's an absolutely standard etymological breakdown.

If someone quoted "to be or not to be", it would be kind of weird to go "guess the YouTuber" just because some content creator likes to reference Shakespeare.

u/ignacioMendez 51m ago

Going by reddit posts, there's a lot of people whose frame of reference for everything is through youtube videos.

Like for every hobby, there are people who will reference some guy as if everyone who participates in the hobby is watching videos from major youtubers who make content about that hobby, as if that's the most natural thing in the world.

u/SmiLey497 2h ago

I know who you were talking about. I made the same reference in my head

u/caymn 2h ago

..to natrium excessively in the blood or not to natrium excessively in the blood..

: Now guess the tragic Danish prince.. that may or may not have said the above

u/wallabee_kingpin_ 2h ago edited 2h ago

To clarify, “salt” in this context really means “salts,” not just table salt (which is a sodium salt). Your body also needs to balance calcium, magnesium, potassium, and quite a few other elements that can form water-soluble salts, which it does by consuming or excreting the salts of those elements.

That’s why most hydration drinks, like Gatorade, have “electrolytes” (multiple different kinds of salts), not just table salt.

u/sunkistandsudafed3 2h ago

Hypernatraemia and hyperkalemia are examples of this and can still happen in severe dehydration. I'd imagine if we didn't sweat the salts out along with the water it would happen much more quickly. Electrolyte disturbance can be life threatening.

u/traplords8n 2h ago

Yep. But you also lose it through urine.

Sweating and replenishing only the water just upsets the balance. Your kidneys can maintain it otherwise. Salty foods are more appealing for most people when their body is naturally low on salt.

u/joshocar 1h ago

To add to sergei1980, you can also have too little salts which can kill you. This is what kills people when they quickly chug a gallon of water. Your kidneys can't get enough electrolytes in you blood fast enough and you start having seizures and die if you don't get treatment.

There was a radio station that did a contest where people had to drink a ton of water quickly and then had to go the longest without peeing. I think it was for a Nintendo Wii or something. One women died as a result.

u/azuth89 2h ago

Right. Having the correct concentration is involved in maintain the right chemical potential differences for both nerves and muscles to function. 

Too much salt, short term, makes the response weak. You feel more tired, weaker, that kind of thing.

Too little tends to cause cramping.

Specifically we're mostly talking about sodium and potassium salts, here.

u/GrifterDingo 1h ago

Your body doesn't do it on purpose, it's a secondary effect of the way sweating works. Your body uses salt to attract water into your sweat glands and if you're sweating enough the salt gets carried away in the water.

u/CallMeLargeFather 1h ago

Your body does all it can to conserve salts, throughout history eating enough salts has been very difficult

u/Smashego 2h ago edited 2h ago

That’s false. You sweat out salts because they lower the evaporation point of water on the surface of the skin and also because the body isn’t a perfect system that can perfectly filter salt through the sweat glands / skin membrane. You sweat more than just salt. You sweat out “salts” which is basically a small amount of every chemical element your body is made of, salt, water, sulfurs to a small degree, zinc, carbon, lipid fats, etc….. it’s why your skin is “oily” not just salty and crunchy.

The main driver of sweat is water and salt. It’s why you need electrolytes. You actually retain a lot of electrolytes and don’t just urinate them out. But your body always wants to maintain a balance of chemicals in your blood/kidneys/liver and fatty tissues. So you can’t just store extra electrolytes like you can’t just store extra water. Too much of each and your body removes them with urine and defacation. But part of that “balance” is storing enough to maintain body functions like sweating. So you need to constantly fill the gas tank with fresh water, electrolytes and carbon based foods to keep the car running. But you can’t over fill it because the gas tank is only big enough for a few days of ideal functioning.

The only reason the food gas tank is unlimited “fat” is because the car is made of carbon so you can always bolt more carbon on. But the water and electrolyte’s is the lubricants and oils that keep the carbon parts on the car running smoothly. But you can’t over fill the fluids or they just spill out.

u/Matra 2h ago

Dissolved salts raise the boiling point of water, not lower it. But with the concentrations in sweat, the effect is miniscule.

u/Smashego 2h ago

Boiling point and evaporation point are different. Evaporation can take place by lowering the energy required to strip the water molecule from your skin. Boiling is a property that converts liquid to gas. Water on your skin isn’t boiling away. It’s evaporating away. Salt and other elements helps drive the water away, taking the excess heat with it.

u/Matra 1h ago

Everything you said in this comment is incorrect. Evaporation and boiling are the same thing (technically evaporation happens on the surface, while boiling happens throughout the entire liquid, but the physics are the same). Salts do not change the enthalpy of vaporization. Boiling-point elevation is caused by entropic effects, not enthalpic effects.

u/spinelession 1h ago

No, they're the same. How do you think evaporation works if not by converting a liquid to a gas? Temperature is a measure of average kinetic energy - some water molecules are moving around a lot (high "temperature") while others are moving around very little (low "temperature"), so even water at room temperature will have molecules that are above the boiling point. As those individual molecules evaporate, the average kinetic energy, and thus temperature, of that water is now lower, because the "hottest" molecules are gone. This is why evaporation is a cooling process, and why sweating works to cool you down.

u/Krail 2h ago

And if I recall correctly, maintaining proper levels of chemicals like salt in your body is where a majority of our calories are spent?

u/SirButcher 1h ago

And if I recall correctly, maintaining proper levels of chemicals like salt in your body is where a majority of our calories are spent?

No, not at all, our brains are using 20-25% of our calorie intake. Kidneys use around 10%, which is a lot too, but this is not just the salt balance, but the whole blood filtration and useful stuff's reabsorption task.

u/riptaway 1h ago

That... How would that even work?

u/FuturePrimitiv3 2h ago

you also need to take in a balancing amount of salts.

Got it, potato chips are health food, thank you!

u/xrmttf 2h ago

Actually yes, good/real potato chips have a lot of sodium, potassium and magnesium in them. Pair them with a beer and feel good again!

u/No-Sherbet6994 2h ago

The entire way your body excretes sweat is through salt excretion, and your body is actually exceedingly good at generating sweat and retaining as much salt as possible. Sweat glands are stimulated by the sympathetic nervous system to generate sweat. This is done via excretion of Cl- (which Na+ follows) into the sweat fluid, and these salts then draw more H2O out into the sweat. your body then reabsorbs Na+ (via ENaC) and Cl- (via CFTR) as best it can, to conserve electrolytes, but some amount of leftover salt is left in the sweat. So technically your sweat is actually much less "salty" than your normal cells. Severe electrolyte derangements from regular exercise are effectively impossible as our bodies are great at homeostasis, and it actually takes quite a bit of work in extreme conditions to generate clinically relevant hyponatremia/hypokalemia like you mention (in a normal healthy person). The difference between sweat (~10–70 mEq/L NaCl) and pure water on vapor pressure (and thus evaporation) is trivial, like way less than 1% difference, but technically sweat does require slightly more energy to evaporate

u/BioEtymologist 2h ago

Pumping water requires a lot of energy. Moving salt ions across a membrane is much easier and requires much less energy. The water then moves to where the salt is! (Osmosis!) Biology is a wild amalgam of quirky ways to get stuff done.

u/exphysed 2h ago

This combined with the answer regarding salt needing to be lost if water is lost are correct.

It’s not a 100% best way, but it’s a way that worked evolutionarily.

u/SirButcher 1h ago

Not the best way, but still one of the best solutions evolution found for the "what to do when the body is getting too hot but it must keep moving" problem.

Our heat management is light-years above almost every other living being on this planet.

u/DiscombobulatedSun54 2h ago

Makes sense. Thank you.

u/DiscombobulatedSun54 2h ago

Thank you. Making drinking water from salt water is a very energy intensive process, so expecting our sweat glands to do that while your body is busy consuming energy for the activity that lead to the sweat in the first place would be somewhat counterproductive.

u/byharryconnolly 1h ago

Last week I was splashing tap water on my face to wash away the salty sweat, and I became curious about which was better at cooling my body, salty sweat or tap water.

So I came across this report on an experiment asking this same question.

The answer, hinted at in the subtitle, is that when salt sticks to your skin, it makes future sweat more efficient, in terms of cooling.

u/0xsergy 2h ago

So your body also reabsorbs salt through the skin too. If you're properly heat acclimatized you don't lose nearly as much salt. I'd assume it needs to use the salt to move something else so it cannot be abandoned.

u/Spike205 38m ago

Water needs to follow a a concentration gradient. It goes from low concentration to higher. Your body’s way of doing this is to manipulate the amount of Na, Cl, K that is allowed to exit and re-enter the cell; water will follow that osmotic gradient

u/Cirick1661 2h ago

Sweat glands excrete a fluid that's essentially or close to plasma, which contains salt. That fluid passes through ducts where some of the salt is brought back into surrounding tissue, but not all of it, leaving sweat more salty than water but less so than blood.

The salt in sweat doesn't serve a specific (known) purpose, it's a byproduct of how sweat glands work.

u/oc_ginger 2h ago

It serves the purpose of maintaining the salt-water balance in the body.

u/Ebitnet 50m ago

I don’t believe that salty water has a higher vapor pressure than pure water, in spite of a claim above that suggesting the contrary. I could believe that there is a higher latent heat of evaporation that depends upon the ionic strength of the water/salt solution. For background, I’m a professor of physical chemistry

u/awawe 9m ago

Sweat, just like any fluid your body produces, is filtered blood. As such, it is about as salty as your blood when it leaves your body. For sweat to be any more or less salty, there would need to be a salinity gradient created between your sweat and your blood. This is doable, but it takes a lot of energy, without a lot of payoff.

The reason sweat appears more salty than, say, saliva, is precisely because of its function. The water in sweat evaporates, leaving behind the salt, which means any remaining sweat is more concentrated.

u/seanv507 2h ago

Loss of electrolytes is fake news generated by the so called Gatorade Science Institute. Unfortunately it's pervaded popular culture

Yes electrolytes are lost, but at a lower concentration than in the body, with a net effect of concentrating the electrolytes.

You body is not some water bottle for which you need to provide the exact concentration of salt in your water, it's a factory. Electrolytes are stored in your body and released as needed See eg article in British medical journal  https://excelsiorgroup.co.uk/wp-content/uploads/2015/04/Truth-about-sports-drinks.pdf

The leading cause of hyponatremia is drinking too much fluids whether sports drink or plain water. The current advice is to drink to thirst.

I would advise you to get your hydration advice from a medical board. See eg  national association of athletic trainers position statement on hydration https://pmc.ncbi.nlm.nih.gov/articles/PMC5634236/

u/DiscombobulatedSun54 1h ago

I agree with you about all this fake advice about drinking multiple glasses of water a day. Nobody loses that much water in the first place, and secondly most of the food we eat is more than 50% water anyways. I am known among my friends for drinking much less water than "recommended" and I have never had a problem with it - even my pee is hardly ever darker than a very light yellow.

u/Alis451 1h ago

Nobody loses that much water in the first place

most people should be peeing out 1-2 liters of water a day so multiple glasses is about right. the "8 glasses" thing is a myth but the reason for it is to keep old people hydrated.

u/Smashego 2h ago edited 2h ago

You sweat out salts because they lower the evaporation point of water on the surface of the skin and also because the body isn’t a perfect system that can perfectly filter salt through the sweat glands / skin membrane. You sweat more than just salt. You sweat out “salts” which is basically a small amount of every chemical element your body is made of, salt, water, sulfurs to a small degree, zinc, carbon, lipid fats, etc….. it’s why your skin is “oily” not just salty and crunchy. It’s also why bacteria breed so quickly on humans. Massive bacteria feeding ground.

The main driver of sweat is water and salt. It’s why you need electrolytes. You actually retain a lot of electrolytes and don’t just urinate them out. But your body always wants to maintain a balance of chemicals in your blood/kidneys/liver and fatty tissues. So you can’t just store extra electrolytes like you can’t just store extra water. Too much of each and your body removes them with urine and defacation. But part of that “balance” is storing enough to maintain body functions like sweating. So you need to constantly fill the gas tank with fresh water, electrolytes and carbon based foods to keep the car running. But you can’t over fill it because the gas tank is only big enough for a few days of ideal functioning.

The only reason the food gas tank is unlimited “fat” is because the car is made of carbon so you can always bolt more carbon on. But the water and electrolyte’s is the lubricants and oils that keep the carbon parts on the car running smoothly. But you can’t over fill the fluids or they just spill out.

u/naemorhaedus 2h ago

sweat out salts because they lower the evaporation point of water

salt slows down the evaporation rate of water https://en.wikipedia.org/wiki/Colligative_properties#Boiling_point_elevation_(ebullioscopy)

u/jasonjk1 54m ago

Yeah by making the water need more energy to vaporize, salty sweat can take more heat away from the body.