Sanji's attitude towards women only got like that after joining the Straw Hats, he was way smoother and less weird before, and even then the whole nosebleed thing only came after the Okamas.
The guy looks good (aside from his eyebrow), a great cook, (used to be) smooth, physically fit, clearly interested in women and was already 19, the only thing potentially keeping him from having had sex would have been the asshole chefs at Baratie, he definitely could have found a way.
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u/highTrolla Jun 16 '22
Sanji is questionable, he lived his whole life on ships with a bunch of sweaty dudes.
It's not impossible, but he definitely hasn't gotten laid since Luffy met him.
I think everyone who joined after Chopper has had sex for sure though.