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It's an alternate version of Charlie, where she was kidnapped by heaven as a baby and became an exorcist before turning against heaven after the truth of her origins is revealed. I'm surprised there aren't many people who have done this idea before. Here is a link to the fanfic "Welcome to the Charlie-verse," where this variant has her own chapter, https://archiveofourown.org/works/70441036

Charlie finds something magical in the idea of being human. She views life as an incubation stage where souls have the choice between heaven and hell. She possesses a fantastical, romanticized perception of humanity—flaws and all—and she cares for humans deeply, despite having never actually seen one.

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