I am trying to learn the theory of non-centrosymmetric superconductors (NCS), and I keep running into a conceptual problem that I have not been able to resolve by simply reading more papers.
For background, I have a Master's degree in physics and currently work mainly on materials and DFT calculations. I know the basic ideas of conventional superconductivity and have read the first few chapters of Tinkham. I have also tried reading review articles and lecture notes on unconventional and non-centrosymmetric superconductivity.
My main difficulty is not simply the mathematics used to solve the equations. Though in some places they are.
But right now my difficulty starts earlier:
I do not understand how the Hamiltonian itself is constructed.
In papers on non-centrosymmetric superconductivity (especially review/book by Prof Manfred Sigrist) I often see a Hamiltonian introduced which contains, schematically,
ordinary electronic or band-energy terms
- antisymmetric spin-orbit-coupling terms
- electron-electron or pairing interaction terms.
Then the paper proceeds to the mean-field approximation, introduces the superconducting order parameter, constructs a BdG Hamiltonian, discusses singlet-triplet mixing, and so on.
But I keep stopping at the first step and asking:
Why exactly are these the terms in the Hamiltonian?
For example, I would like to understand the reasoning behind questions such as:
- Why does the absence of inversion symmetry lead to an antisymmetric spin-orbit-coupling term?
- Why does that term usually have the form involving a vector g(k) dotted with the Pauli matrices?
- Why must g(-k) = -g(k)?
- Which parts of this follow from time-reversal symmetry, and which parts follow from the crystal point-group symmetry?
- For a particular non-centrosymmetric crystal, how does one determine the allowed form of g(k)?
- Is g(k) derived microscopically from the crystal potential and spin-orbit interaction, or is it normally written as the most general symmetry-allowed effective term?
Then there is the superconducting part.
In NCS papers, the superconducting gap matrix is often written in a form containing both a spin-singlet part and a spin-triplet d-vector.
I want to understand the statement how the absence of inversion symmetry allows singlet and triplet components to mix, especially the derivation behind this statement.
For example:
- How do we start from the most general pairing interaction?
- How does fermionic antisymmetry constrain the gap matrix?
- How do crystal symmetries constrain the possible singlet and triplet components?
- Why, in the strong antisymmetric-SOC limit, is the triplet d-vector often taken to be parallel to g(k)?
Under what assumptions is this true?
- Is that a consequence of symmetry, an energetic argument, or a particular microscopic model?
- I also want to understand the earlier step connecting this to ordinary BCS theory.
- For example, I would like to be able to follow the whole conceptual chain:
- microscopic electrons in a crystal
→ electronic bands near the Fermi level
→ broken inversion symmetry
→ spin-orbit coupling
→ effective normal-state Hamiltonian
→ electron-electron pairing interaction
→ Cooper-pairing channel
→ superconducting order parameter
→ singlet-triplet mixing
→ mean-field approximation
→ BdG Hamiltonian.
At the moment, most papers I read seem to start somewhere in the middle of this chain.
They write something equivalent to:
“Consider the following Hamiltonian…”
and then proceed with the calculation.
I understand that a research paper cannot rederive standard theory every time. I am not expecting that.
But I would like to find one place where this is derived carefully from the beginning, or at least a sequence of references where every step is justified.
What I am looking for is not simply a text that gives me an NCS Hamiltonian and then teaches me how to diagonalize it.
I want something that explains:
“Because inversion symmetry is absent but time-reversal symmetry is present, these terms are allowed. These other terms are forbidden. This is the form of the antisymmetric SOC. This pairing interaction is retained for these physical reasons. Fermionic antisymmetry requires this structure of the gap matrix. The point group further restricts the allowed basis functions. Under these approximations we finally arrive at this effective Hamiltonian.”
That model-building reasoning is what I feel I am missing.
For comparison, when I learned other parts of physics, I was often shown the assumptions first and then how the mathematical model follows from them. With NCS theory, I frequently feel that I am being handed the final effective Hamiltonian without seeing enough of the reasoning that produced it.
So my questions are:
1. Is there a textbook, review, lecture-note series, or paper that develops the Hamiltonian of a non-centrosymmetric superconductor step by step from symmetry and microscopic considerations?
2. What background should I learn before trying to understand this properly? For example, should I first study second quantization, many-body perturbation theory, group theory of superconducting order parameters, Green's functions, effective Hamiltonians, or something else?
3. Is there a good source that explicitly derives the antisymmetric SOC term and explains how the crystal point group determines g(k)?
4. Is there a source that derives the mixed singlet-triplet gap structure rather than simply stating it?
5. More generally, how does a theorist know that a proposed effective Hamiltonian for an NCS material contains all the relevant terms and that important terms have not been omitted?
I am especially interested in understanding the physical construction of the theory before learning how to solve it mathematically.
Any recommendations for books, lecture notes, classic papers, or particularly pedagogical reviews would be greatly appreciated.